By Valery P. Kukhar, Harry R. Hudson

Aminophosphinic and aminoposphonic acids, man made analogs to traditional amino acids, have attained a place of prominence in research--particularly in study related to the amendment of physiological procedures in residing organisms.

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03 (s, CsH s) [73] IR (Nujol): 1088vs, br (SO), 1158vs, 1356vs (both S02), 2035vs, 2070vs (both CO), 3295w, br (NH) [73] [Fp(CH:z=CHCH 2S(=O)NHS02CH3)]BF.. 25 (m, 2 H, CsH s) [36] IR (KBr): 2020, 2045 (both CO) [36] deprotonation with N(C2Hsh in CH 3N02 solution at O°C afforded 72% of FpCH 2CH=CHOCeHs [36] [Fp(CH:z=CHCH 20 2CCH3)]BF.. j+[BF 4r [BF 4r I (71 %) [28], VI (not isolated) [36] yellow crystals, dec. 18 (s's, both CO) [28] IR (KBr): 2000, 2049 (both CO) [28] deprotonation with N(C2Hsb in CH 2CI2 at O°C afforded 97% of FpCH 2CH=CHOCH3 [28, 36] reduction with one equivalent NaBH..

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